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About a century ago, the Swedish physical scientist Arrhenius proposed a law of classical chemistry that relates chemical reaction rate to temperature. According to the Arrhenius equation, chemical reaction are increasingly unlikely to occur as temperatures approach absolute zero, and at absolute zero (zero degrees Kelvin, or minus 273 degrees Celsius) reactions stop. However, recent experimental evidence reveals that although the Arrhenius equa- tion is generally accurate in describing the kind of chemical reaction that occurs at relatively high temperatures, at temperatures closer to zero a quantum-mechanical effect known as tunneling comes into play; this effect accounts for chemical reactions that are forbidden by the principles of classical chemistry. Specifically, entire molecules can "tunnel" through the barriers of repulsive forces from other molecules and chemically react even though these molecules do not have sufficient energy, according to classical chemistry, to overcome the repulsive barrier.
The rate of any chemical reaction, regardless of the temperature at which it takes place, usually depends on a very important characteristic known as its activation energy. Any molecule can be imagined to reside at the bottom of a so-called potential well of energy. A chemical reaction corresponds to the transition of a molecule from the bottom of one potential well to the bottom of another. In classical chemistry, such a transition can be accomplished only by going over the potential barrier between the wells, the height of which remains constant and is called the activation energy of the reaction. In tunneling, the reacting molecules tunnel from the bottom of one to the bottom of another well without having to rise over the barrier between the two wells. Recently researchers have developed the concept of tunneling temperature: the temperature below which tunneling transitions greatly outnumber Arrhenius transitions, and classical mechanics gives way to its quantum counterpart.
This tunneling phenomenon at very low temperatures suggested my hypothesis about a cold prehistory of life: the formation of rather complex organic molecules in the deep cold of outer space, where temperatures usually reach only a few degrees Kelvin. Cosmic rays (high-energy protons and other particles) might trigger the synthesis of simple molecules, such as interstellar formaldehyde, in dark clouds of interstellar dust. Afterward complex organic molecules would be formed, slowly but surely, by means of tunneling. After I offered my hypothesis, Hoyle and Wickramasinghe argued that molecules of interstellar form- aldehyde have indeed evolved into stable polysaccharides such as cellulose and starch. Their conclusions, although strongly disputed, have generated excitement among investigators such as myself who are proposing that the galactic clouds are the places where the prebiological evolution of compounds necessary to life occurred.
RosieZhang
[数学 ]【新版】冲分救命题 -11998
The integers a, b, and c are positive, and a>b>c. When a, b, and c are divided by 3, the remainders are 0, 1, and 1, respectively.
[数学 ]【新版】冲分救命题 -11997
For all positive even integers n. n* represents the product of all even integers from 2 to n, inclusive. For example, 12*=12×10×8×6×4×2. What is the greatest prime factor of 20*+22*?
[数学 ]【新版】冲分救命题 -11996
[数学 ]【新版】冲分救命题 -11995
[数学 ]【新版】冲分救命题 -11994
In a game, the cards in a certain deck are distributed to players one at a time until each player has the same number of cards and there are not enough cards left in the deck to distribute one more card to each player. The number of cards in the deck is between 60 and 100. If the cards in the deck are distributed o 5 players, 2 cards will be left in the deck. If the cards in the deck are distributed to 6 players, 4 cards will be left in the deck. If the cards in the deck are distributed to 7 players, how many cards will be left in the deck?
[数学 ]【新版】冲分救命题 -11993
Let a be the greatest integer such that is a factor of 1,500, and let b be the greatest integer such that is a factor of 33,333,333. Which of the following statements are true? Indicate all such statements.
[数学 ]【新版】冲分救命题 -11992
A set consists of all three-digit positive integers with the following properties.Each integer is of the form JKL,where J,K,and I are digits;all the digits are nonzero;and the two-digit integers JK and KL are each divisible by 9.How many integers are in the set?
[数学 ]【新版】冲分救命题 -11991
[数学 ]【新版】冲分救命题 -11990
The number of children in a certain family is a prime number less than 10. The number of boys in the family is greater than the number of girls, and the number of boys is a prime number. If at least 1 of the children in the family is a girl, which of the following could be the number of boys in the family?Indicate all such numbers.
[数学 ]【新版】冲分救命题 -11989
[数学 ]【新版】冲分救命题 -11988
x and y are integers.
[数学 ]【新版】冲分救命题 -11987
x and y are integers.
[数学 ]【新版】冲分救命题 -11986
a and b are distinct odd prime numbers.
[数学 ]【新版】冲分救命题 -11985
When the integer n is divided by 33, the remainder is 24. Which of the following must be a divisor of n?
[数学 ]【新版】冲分救命题 -11984
4.What is the length of an edge of the smallest solid cube that can be made by placing together solid rectangular blocks of size 7 by 6 by 3?
[数学 ]【新版】冲分救命题 -11983
Light travels at approximately 186,000 miles per second.Which of the following is closest to the number of miles that light travels in 3 hours.
[数学 ]【新版】冲分救命题 -11982
The number n is the least positive integer for which 108n is the square of an intege
[数学 ]【新版】冲分救命题 -11981
The number n is the least positive integer for which 108n is the square of an intege
[数学 ]【新版】冲分救命题 -11980
If x=2y+1, and y=2w, where w, x, and y are integers, which of the following must be an odd integer?
[数学 ]OG -11979
If x=2y+1, and y=2w, where w, x, and y are integers, which of the following must be an odd integer?
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